Organometallics

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  Año 2005, Vol. 24, Número 8

  • Editor's Page

    D. Seyferth

    pág. 1785

    

  • A New Generation of pi-Basic Dearomatization Agents

    J. M. Keane, W. D. Harman

    págs. 1786-1798

    

  • Novel Iridium Complexes Containing 2,6-Bis(oxazoline)pyridine Ligands: Synthesis and Reactivity of the Diolefin Iridium(I)Complex[Ir(eta^2-C~2H~4)~2{kappa^3N,N,N-(S,S)-i-Pr-pybox}][PF~6] ((S,S)-i-Pr-pybox = 2,6-Bis(4'-(S)-isopropyloxazolin-2'-yl)pyridine)

    J. Diez, María Pilar Gamasa Bandrés

    págs. 1799-1802

    

  • A Cationic Three-Coordinate Iron(II) Complex and the Reaction of beta-Diketiminate with Ethyl Diazoacetate

    E. A. Gregory, R. J. Lachicotte

    págs. 1803-1805

    

  • A New C~2-Symmetric Ligand for ansa-Metallocene Chemistry: Synthesis and X-ray Crystal Structure of the ansa-Stannocene Complex rac-[(CHBu^t)~2-(C~5H~2Bu^t~2)~2]Sn

    C. J. Pitotti

    págs. 1806-1808

    

  • X-ray, ^1^3C NMR, and DFT Studies on a Ruthenium(IV) Allyl Complex. Explanation for the Observed Control of Regioselectivity in Allylic Alkylation Chemistry

    R. Hermatschweiler

    págs. 1809-1812

    

  • Reactions of Sn(NMe~2)~2 with Primary Aryl Phosphides, ArPH^-: Synthesis and Structures of the Heteroleptic Cages [{(PhP-PPh)Sn(mu-PPh)}~2(Na·PMDETA)~4 and [{Sn(mu~3-Ppy)}~3{Sn(mu~3,mu~1-pyP-Ppy)}~3]

    R. A. Kowenicki, F. Garcia, A. D. Hopkins

    págs. 1813-1818

    

  • Supramolecular Triruthenium Cluster-Based Benzene Hydrogenation Catalysis: Fact or Fiction?

    C. M. Hagen, L. Vieille-Petit

    págs. 1819-1831

    

  • Synthesis and Characterization of a Dicationic Dihydrogen Complex of Iridium with a Bis-carbene Ligand Set

    M. Vogt, D. M. Heinekey, V. Pons

    págs. 1832-1836

    

  • C-H versus Ir-X (X = H, Cl) Reactivity in a Tropylium PCP Pincer Iridium Complex

    A. M. Winter

    págs. 1837-1844

    

  • Density Functional Characterization of Reactions of Bimetallic Carbenes Pt-MCH~2^+ (M = Pt, Au) with NH~3 in the Gas Phase

    F. Xia, K. Zeng, J. Chen

    págs. 1845-1851

    

  • Ultrafast Infrared Mechanistic Studies of the Interaction of 1-Hexyne with Group 6 Hexacarbonyl Complexes

    J. E. Shanoski

    págs. 1852-1859

    

  • Nitrogen-Nitrogen Double Bond Cleavage of Azobenzene by a Triruthenium Pentahydrido Complex, (Cp'Ru)~3(mu~3-H)~2-(mu-H)~3 (Cp' = eta^5-C~5Me~5), and Catalytic Hydrogenation of Azobenzene and 1,2-Diphenylhydrazine

    Y. Nakajima

    págs. 1860-1866

    

  • Intramolecular Coupling of eta^2-Iminoacyls on Zirconium Bis(aryloxides) and Calix[4]arenes: Revised Mechanism by DFT Calculations and Car-Parrinello Molecular Dynamics Simulations

    A. Sgamellotti, F. De Angelis

    págs. 1867-1875

    

  • Tungsten(0) eta^2-Thiophene Complexes: Dearomatization of Thiophene and Its Facile Oxidation, Protonation, and Hydrogenation

    D. A. Delafuente

    págs. 1876-1885

    

  • Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality

    B. C. Bailey, L. A. Watson, J. Tomaszewski, F. Basuli

    págs. 1886-1906

    

  • Electrospray Ionization Tandem Mass Spectrometric Determination of Ligand Binding Energies in Platinum(II) Complexes

    L. A. Hammad

    págs. 1907-1913

    

  • Deuterium Quadrupolar Coupling Constants of Deuteride Bridging Ligands: A Study on Rhenium Hydrido Carbonyl Clusters

    T. Beringhelli

    págs. 1914-1918

    

  • Synthesis of Acyclic NPNCN Systems and Metalation Reactions with Organolithium, -magnesium, and -aluminum Reagents

    T. Chivers, M. C. Copsey, C. Fedorchuk

    págs. 1919-1928

    

  • Synthesis of Molybdenum(VI) Monoimido Alkyl and Alkylidene Complexes

    T. S. Pilyugina

    págs. 1929-1937

    

  • Can Steric Effects Induce the Mechanism Switch in the Rhodium-Catalyzed Imine Boration Reaction? A Density Functional and ONIOM Study

    V. P. Ananikov

    págs. 1938-1946

    

  • Octahedral Bis(phenoxy-imine)tin(IV) Alkyl Complexes: Synthesis, Characterization, and Reactivity toward Ionizing Species and Ethylene

    D. Pappalardo, L. Annunziata

    págs. 1947-1952

    

  • Aluminum Complexes with Sulfide-Linked Bis(phenolato) Ligands: Unusual Structure and Reactivity of the Methyl Bis(phenolato) Complex "[Al-(tbmp)Me]" (tbmp = 2,2'-Thiobis(6-tert-butyl-4-methylphenolato))

    W. Braune

    págs. 1953-1958

    

  • Synthesis and Reactivity of New kappa^2-[P,N]Pt(II) Complexes of Diisopropylphosphino-Substituted 2-Dimethylaminoindene

    R. McDonald, B. M. Wile, M. J. Ferguson

    págs. 1959-1965

    

  • Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2'-Azobispyridine): Stabilization of the Radical Intermediate and of the Os^0Os^I^I State

    F. Baumann

    págs. 1966-1973

    

  • Reactivity of the Unsaturated Complex [(C~6Me~6)~2Ru~2(mu~2-H)~3]^+ toward Phosphines: Synthesis and Molecular Structure of the Dinuclear Cations [(C~6Me~6)~2Ru~2(mu~2-PR~2)(mu~2-H)~2]^+ and Characterization of the P-C Bond Activation Intermediate [(C~6Me~6)~2Ru~2(mu~2-PPh~2)(mu~2-H)(mu~2-Ph)]^+

    M. J.-L. Tschan

    págs. 1974-1981

    

  • Facile Transformations of Lanthanocene Alkyls to Lanthanocene Thiolate, Sulfide, and Disulfide Derivatives by Reaction with Elemental Sulfur

    J. Zhang, C. Pi, Y. Li

    págs. 1982-1988

    

  • Accessing Lanthanide Diiodide Reactivity for Coupling Alkyl Chlorides to Carbonyl Compounds via the NdI~3/Alkali Metal Reduction System

    P. S. Workman, W. J. Evans

    págs. 1989-1991

    

  • Synthesis, Stereoselective Reactions, and Reactivity of 9-Triptycyldimethyltin Hydride

    M. B. Faraoni, V. I. Dodero, Darío Cesar Gerbino

    págs. 1992-1995

    

  • Ligand Metallation during the Reduction of a Thorium(IV) Amide Complex

    S. Gambarotta, A. Athimoolam

    págs. 1996-1999