Organometallics

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  Año 2006, Vol. 25, Número 5

  • Editor's Page

    D. A. Sweigart

    pág. 1059

    

  • Modern Ate Chemistry: Applications of Synergic Mixed Alkali-Metal-Magnesium or -Zinc Reagents in Synthesis and Structure Building

    R. E. Mulvey

    págs. 1060-1075

    

  • Chemoselective Deprotonations of a Cationic Zirconium Primary Amido Complex to Either a Neutral Zirconium Terminal Imido or a Noninterconverting Tautomer

    Denis Kissounko, Albert Epshteyn, James C. Fettinger, Lawrence R. Sita

    págs. 1076-1078

    

  • Slip-Inversion-Slip Mechanism of Phosphametallocene Isomerization. Spectroscopic Characterization of an (eta^1-Phospholyl)titanium Complex. Synthesis and Structures of Chiral Mono(phospholyl)titanium Complexes

    Y. J. Ahn, R. J. Rubio, T. K. Hollis

    págs. 1079-1083

    

  • Formation of PPh~2C~6F~5 through Phosphido Platinum and/or Palladium(III) Intermediates

    N. Chaouche, I. Ara

    págs. 1084-1091

    

  • Carbon-Hydrogen Bond Activation with a Cyclometalated Zirconocene Hydride: Mechanistic Differences between Arene and Alkane Reductive Elimination

    W. H. Bernskoetter

    págs. 1092-1100

    

  • Addition of H~2 on (Sulfur, Phosphorus, Sulfur)-Pincer-Based Rhodium(I), Iridium(I), Palladium(II), and Platinum(II) Complexes: Reactivity and Regioselectivity

    L. Ricard, M. Doux, P. Le Floch

    págs. 1101-1111

    

  • [(^tBu~2PCH~2SiMe~2)~2N]RuMe~2: Synthesis and Reactivity of an Unsaturated Ruthenium Dialkyl Radical Species

    M. J. Ingleson

    págs. 1112-1119

    

  • C-H Oxidative Addition of Bisimidazolium Salts to Iridium and Rhodium Complexes, and N-Heterocyclic Carbene Generation. A Combined Experimental and Theoretical Study

    M. Poyatos, Monica Viciano Miralles

    págs. 1120-1134

    

  • Stabilization of a Dialkylstannylene by Unusual B-H···Sn gamma-Agostic-Type Interactions. A Structural, Spectroscopic, and DFT Study

    W. McFarlane, K. Izod

    págs. 1135-1143

    

  • Density Functional Study on the Regioselectivity of Styrene Polymerization with an ansa-Metallocene Catalyst

    S. H. Yang

    págs. 1144-1150

    

  • Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene: Influence of Electronic and Steric Effects on Enantioselectivity and Catalyst Design via Hybrid QM/MM Molecular Dynamics Simulations

    A. Magistrato

    págs. 1151-1157

    

  • Reactions of CpArCHCHArCp with Ru~3(CO)~1~2: An Unexpected Cleavage of a Bridging C-C Bond and Coupling of the Two Cyclopentadienyl Rings to Fulvalene Diruthenium Complexes

    B. Li, B. Wang

    págs. 1158-1166

    

  • Reactions of Cyclopentadienyl-Amidinate Titanium Imido Compounds with CS~2, COS, Isocyanates, and Other Unsaturated Organic Compounds

    A. E. Guiducci

    págs. 1167-1187

    

  • Sila-venlafaxine, a Sila-Analogue of the Serotonin/Noradrenaline Reuptake Inhibitor Venlafaxine: Synthesis, Crystal Structure Analysis, and Pharmacological Characterization

    J. S. Mills, J. G. Montana, J. O. Daiss, C. Burschka, J. B. H. Warneck, G. A. Showell

    págs. 1188-1198

    

  • 1,1'-P/O-Ferrocenyl Ligands in Palladium-Catalyzed Suzuki Coupling of Aryl Chlorides

    T. S. A. Hor, Z. Weng, S. Teo

    págs. 1199-1205

    

  • Reactions of Diorganomagnesium Compounds and Cryptands or 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane: Formation of RMg-(macrocycle)^+ Cations and Organomagnesate Anions

    Anthony D. Pajerski, D. M. Kushlan

    págs. 1206-1212

    

  • Nickel Complexes Based on Tridentate Pyrazolyl Ligands for Highly Efficient Dimerization of Ethylene to 1-Butene

    M. C. A. Kuhn, N. Ajellal, A. D. G. Boff

    págs. 1213-1216

    

  • Palladium-Catalyzed Pathways to Aryl-Substituted Indenes: Efficient Synthesis of Ligands and the Respective ansa-Zirconocenes

    A. Y. Lebedev, V. V. Izmer, M. V. Nikulin

    págs. 1217-1229

    

  • The PPh~3-Substituted Hydroxycyclopentadienyl Ruthenium Hydride [2,5-Ph~2-3,4-Tol~2(eta^5-C~4COH)]Ru(CO)(PPh~3)H Is a More Efficient Catalyst for Hydrogenation of Aldehydes

    N. A. Strotman, C. P. Casey

    págs. 1230-1235

    

  • PPh~3-Substituted [2,5-Ph~2-3,4-Tol~2(eta^5-C~4COH)]Ru(CO)(PPh~3)H Exhibits Slower Stoichiometric Reduction, Faster Catalytic Hydrogenation, and Higher Chemoselectivity for Hydrogenation of Aldehydes over Ketones Than the Dicarbonyl Shvo Catalyst

    N. A. Strotman, C. P. Casey

    págs. 1236-1244

    

  • pi Complexes of Fluorous Alkynes, Cyclobutadienes, and Benzenes: Syntheses and Phase Properties of Cobalt and Chromium Tricarbonyl Adducts

    C. S. Consorti, L. V. Dinh

    págs. 1245-1251

    

  • Octahedral and Bicapped-Tetrahedral Silicon Configurations in the Solid State and Their Dynamic Coexistence in Solution

    I. Kalikhman, M. Botoshansky, B. Gostevskii

    págs. 1252-1258

    

  • Functionalization of Metal-Protected Chiral Phosphines via Simple Organic Transformations

    W.-C. Yeo, J. J. Vittal

    págs. 1259-1269

    

  • Living Polymerization of Bulky Aryl Isocyanide with Arylrhodium Complexes

    K. Onitsuka, M. Yamamoto

    págs. 1270-1278

    

  • Coupling of N-Heterocycle-Fused Enyne Aldehydes with gamma,delta-Unsaturated Fischer Carbene Complexes

    W. F. K. Schnatter, J. Zhang, Y. Zhang

    págs. 1279-1284

    

  • Reaction Mechanism of Transmetalation between Tetraorganostannanes and Platinum(II) Aryltriflate Complexes. Mechanistic Model for Stille Couplings

    P. Nilsson

    págs. 1285-1292

    

  • Formation of a Vinyliminium Palladium Complex by C-C Coupling in Vinylcarbene Palladium Aryl Complexes

    Ana Carmen Albéniz Jiménez

    págs. 1293-1297

    

  • Mixed Dicarboxylato-Bis(carbene) Complexes of Palladium(II): Synthesis, Structures, Trans-Cis Isomerism, and Catalytic Activity

    H. V. Huynh

    págs. 1298-1302

    

  • Reaction of Nitromethane with an Iridium Pincer Complex. Multiple Binding Modes of the Nitromethanate Anion

    X. Zhang, T. J. Emge

    págs. 1303-1309