Organometallics

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  Año 2004, Vol. 23, Número 10

  • Editor's Page

    D. Seyferth

    pág. 2209

    

  • Transition-Metal Silyl Complexes and Chemistry in the Reactions of Silanes with Transition-Metal Complexes

    X. Yu, L. A. Morton

    págs. 2210-2224

    

  • Isolation of Bis(eta^2-nitrato)(eta^4-cyclobutadiene)cobalt(II) Complexes from the Oxidation of Sterically Hindered CpCo-Stabilized Cyclobutadiene Complexes

    F. Rominger, C. Schaefer, R. Gleiter

    págs. 2225-2227

    

  • Diastereoselective Palladium-Mediated Phosphetane Ring Opening and Pd-to-P Phenyl Migration. Synthesis of a New P-Stereogenic C~2-Symmetric Diphosphine Ligand

    T. J. Brunker, J. R. Moncarz

    págs. 2228-2230

    

  • Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes

    R. T. Ruck, R. G. Bergman

    págs. 2231-2233

    

  • Scandium-Catalyzed Intramolecular Hydroamination. Development of a Highly Active Cationic Catalyst

    F. Lauterwasser

    págs. 2234-2237

    

  • IAN Amines: Chiral C~2-Symmetric Zirconium(IV) Complexes from Readily Modified Axially Chiral C~1-Symmetric beta-Diketimines

    S. B. Cortright

    págs. 2238-2250

    

  • New Polyhedral Zinc Siloxanes: Synthesis and X-ray Crystal Structures of Zn~8Me~7(dioxane)~2(O~3SiR)~3 and [Zn~7Me~2-(THF)~5(O~3SiR)~4] [R = (2,6-iPr~2C~6H~3)-N(SiMe~3)]

    G. Anantharaman, V. Chandrasekhar

    págs. 2251-2256

    

  • Preparation of an Aquocobaloxime 1,3-Dienyl Complex and Its Diels-Alder Reactions in Water and Organic Solvents

    C. J. Tucker, M. E. Welker

    págs. 2257-2262

    

  • Ruthenium(II) sigma-Acetylide and Carbene Complexes Supported by the Terpyridine-Bipyridine Ligand Set: Structural, Spectroscopic, and Photochemical Studies

    C.-Y. Wong, M. C. W. Chan

    págs. 2263-2272

    

  • Formation of New eta^5-Rhodium(III) Complexes from eta^5-Rh(I) Rhodacarborane-Containing Charge-Compensated Ligands

    Rosario Nuñez Aguilera, Òscar Tutusaus Santandreu, Francesc Teixidor Bombardo

    págs. 2273-2280

    

  • Structure and Dynamics in a Bis(perfluoroalkyl)triazapentadiene Methylmercury Compound

    A. R. Siedle

    págs. 2281-2286

    

  • Role of Cation-Anion Interactions in Ionic Complexes Containing [Pd{C~6H~3-(CH~2NMe~2)~2-2,6}(OH~2)]^ ^- and [{Pd(C~6H~3-(CH~2NMe~2)~2-2,6)}~2(mu-Cl)]^- Cations

    A. V. Chuchuryukin, J. van den Broeke, J. J. H. Heeringa

    págs. 2287-2294

    

  • 3,5-Dialkyl Effect on Enantioselectivity in Pd Chemistry: Applications Involving Both Bidentate and Monodentate Auxiliaries

    P. S. Pregosin, P. Dotta, P. G. A. Kumar

    págs. 2295-2304

    

  • Stabilization of Organosilanetriols in Amine Matrices: Trapping Intermediates between RSi(OH)~3 and (RSiO~3)^3^- Anions

    G. Prabusankar

    págs. 2305-2314

    

  • Arene Hapticity in (C~6H~6)Cr(CO)~n (n = 1-5) Complexes: A DFT Study of Singlet and Triplet Energy Surfaces

    E. Weitz, R. Cohen, J. M. L. Martin

    págs. 2315-2325

    

  • Chiral-at-Metal Osmium(VI) Phosphine Complexes

    P. A. Shapley, D. H. Pool

    págs. 2326-2335

    

  • Mechanism of the Methylene Transfer Reaction. C-C Activation and Reductive Elimination in One System. A DFT Study

    J. M. L. Martin, D. Milstein, R. Cohen

    págs. 2336-2342

    

  • Organometallics versus P~4 Complexes of Group 11 Cations: Periodic Trends and Relativistic Effects in the Involvement of (n-1)d, ns, and np Orbitals in Metal-Ligand Interactions

    I. Krossing, H.-C. Tai

    págs. 2343-2349

    

  • Toward a More Detailed Understanding of Oxidative-Addition Mechanisms: Combined Experimental and Quantum-Chemical Study of the Insertion of Titanium Atoms into C-H, Si-H, and Sn H Bonds

    T. M. Greene, A. Bihlmeier, H.-J. Himmel

    págs. 2350-2361

    

  • Synthesis of Chiral Cyrhetrenes and Their Application in Asymmetric Catalysis

    L. Xiao, L. Hintermann, C. Bolm

    págs. 2362-2369

    

  • Sequential Insertion of Formaldehyde and Carbon Monoxide into a Sulfide-Bridged Pd-Ge Bond Followed by Reductive Elimination To Form a [1,3,2]Oxathiagermolan-4-one

    Jeff W. Kampf, Z. T. Cygan, M. M. B. Holl

    págs. 2370-2375

    

  • Structural Diversity of the Tris(di-tert-butylmethylsilyl)stannyl Anion: Monomeric vs Dimeric, Lithium Coordinated vs Lithium Free

    T. Fukawa, M. Nakamoto

    págs. 2376-2381

    

  • Dimeric Aluminum Chloride Complexes of N-Alkoxyalkyl-beta-ketoimines: Activation with Propylene Oxide To Form Efficient Lactide Polymerization Catalysts

    S. Doherty, R. J. Errington

    págs. 2382-2388

    

  • Molecular Design of Bis-Chelate N-Donor-Stabilized Silaethenes: Theoretical Study of 1,1-Bis[N-(dimethylamino)acetimidato]silene

    E. F. Belogolova, V. A. Pestunovich, V. F. Sidorkin

    págs. 2389-2396

    

  • Stereochemistry of Disilanylene-Containing Cyclic Compounds. Synthesis and Reactions of cis- and trans-3,4-Benzo-1,2-di(tert-butyl)-1,2-dimethyl-1,2-disilacyclo but-3-ene

    I. Miyahara, J. Ikadai, J. Sakata, A. Naka

    págs. 2397-2404

    

  • Effects of Ligand Substitutions on the Rotation Rate of Indenyl Ligands in Bis(2-arylindenyl)zirconocenes by NMR Line-Shape Analysis and Relaxation in the Rotating Frame

    M. B. France, G. M. Wilmes

    págs. 2405-2411

    

  • Platinum-Catalyzed Wacker Oxidation of Alkenes Utilizing cis-Pt(Cl)~2(TPPTS)~2 (TPPTS = P(m-C~6H~4SO~3Na)~3)

    D. S. Helfer, J. D. Atwood

    págs. 2412-2420

    

  • Bis(iminophosphorano)methane Derivatives as Precursors of Unusual Ruthenium Carbene Complexes: A Synthetic and DFT Study

    Victorio Cadierno

    págs. 2421-2433

    

  • Activation Volumes of Substitution Reactions on Neutral and Cationic Organometallic Platinum(IV) Complexes: Definite Proof of Selective Associative Activation.

    A. E. Merbach, C. Gallego, G. González, M. Martinez

    págs. 2434-2438