Synthesis and Stereochemical/Electrochemical Analyses of Cuboctahedral-Based Pd23(CO) x (PR3)10 Clusters (x=20 with R3=Bu n 3, Me2Ph; x=20, 21, 22 with R3=Et3): Geometrically Analogous Pd23(PEt3)10 Fragments with Variable Carbonyl Ligations and Resulting Implications