Resumen de Rigidochromism in metal-centered emission of Rh(III) complexes

Leslie S. Forster, John V. Rund

• A thermally induced redshift in a metal-centered 3T1->1A1 emission is due to population of the higher energy component of 3T1 , split by a low symmetry field. The population of this level is increased by solvent motion and the redshift then appears as rigidochromism.