An ion-pair complex [Cd(en)3]22+[Ag4(mnt)4]4− and three mixed metallic coordination polymers MNi(mnt)2 [M = Pd(II), 2Ag(I) or Hg(II); mnt2−=maleonitriledithiolate] have been prepared and characterized using IR, UV–Visible and conductivity techniques. All of the complexes exhibit pressed pellet and show electrical behaviour of semiconductors over 303–393 K range.
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