Diamagnetic Anisotropy:: Two Iron Complexes as Laboratory Examples

• Ignacio Fernández ^[1] ; Jorge Fernando Fernández Sánchez ^[2]
  1. [1] Universidad de Almería

     Universidad de Almería

     Almería, España

     
  2. [2] Universidad de Granada

     Universidad de Granada

     Granada, España

     
• Localización: Journal of chemical education, ISSN 0021-9584, Vol. 87, Nº 3 (March), 2010, págs. 320-322
• Idioma: inglés
• Texto completo no disponible (Saber más ...)
• Resumen

  • There are relatively few experiments describing the NMR properties of bis(amine) iron(II) phthalocyanine complexes. Several features make this experiment attractive: First, it nicely illustrates the diamagnetic anisotropy phenomena, providing both students and teachers an opportunity to gain insight into aspects such as phase correction and integration. Second, it gives the students hands-on experience with the NMR spectrometer and general aspects of one- and two-dimensional spectra processing. Finally, inorganic coordination synthetic work is needed and proved to be simple and high yielding.