Explorations in Organometallic Synthesis:: Characterization and Structure Determinations of Binuclear Phosphine-Bridged Complexes of Platinum Using Multinuclear NMR and IR Spectroscopy

• Kimberly A. Brittingham ^[1] ; Serge Schreiner ^[1] ; Thomas N. Gallaher ^[2]
  1. [1] Randolph–Macon College

     Randolph–Macon College

     Estados Unidos

     
  2. [2] James Madison University

     James Madison University

     Estados Unidos

     
• Localización: Journal of chemical education, ISSN 0021-9584, Vol. 72, Nº 10 (October), 1995, págs. 941-944
• Idioma: inglés
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• Resumen

  • A multi-step experiment has been developed for the inorganic chemistry laboratory in which students synthesize and characterize various bimetallic platinum complexes. Three 3-hr lab periods are required for the entire experimental/characterization process. Experimental techniques are not elaborate, but require the exclusion of oxygen with a nitrogen atmosphere as well as adequate hood ventilation. The isolated compounds are identified and characterized using infrared spectroscopy and multinuclear NMR.