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Resumen de The Gibbs Function, Spontaneity, and Walls

R.J. Tykodi

  • For the expansion-into-the-vacuum process involving a saturated vapor, previously analyzed by Schomaker and waser and by myself, I assert that in general Delta G (composite) is undefined and that for the special case of bulbs with perfectly rigid walls Delta G (composite) is weakly positive. I show that the seemingly contradictory results of Schomaker and Waser are merely the consequences of their use of eccentric or anti-conventional terminology: they calculate the change in the Availability function for the process and call that change "Delta G (composite)".


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