Layered and scrolled nanocomposites with aligned semi-infinite graphene inclusions at the platelet limit

• Autores: Pingwei Liu, Zhong Jin, Georgios Katsukis, Steven Shimizu
• Localización: Science, ISSN 0036-8075, Vol. 353, Nº 6297, 2016, págs. 364-367
• Idioma: inglés
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• Resumen

  • Two-dimensional (2D) materials can uniquely span the physical dimensions of a surrounding composite matrix in the limit of maximum reinforcement. However, the alignment and assembly of continuous 2D components at high volume fraction remain challenging. We use a stacking and folding method to generate aligned graphene/polycarbonate composites with as many as 320 parallel layers spanning 0.032 to 0.11 millimeters in thickness that significantly increases the effective elastic modulus and strength at exceptionally low volume fractions of only 0.082%. An analogous transverse shear scrolling method generates Archimedean spiral fibers that demonstrate exotic, telescoping elongation at break of 110%, or 30 times greater than Kevlar. Both composites retain anisotropic electrical conduction along the graphene planar axis and transparency. These composites promise substantial mechanical reinforcement, electrical, and optical properties at highly reduced volume fraction.