Resumen de The ν6=1 state of fluoroform, HCF3: analysis of the rotational and vibrational spectra
G. Graner, G. Duxbury, J. Cosle¿ou, A. Ceausu-Velcescu, J. Demaison, H. Bu¿rger
An analysis of the ν6=1 state of fluoroform is performed using rotational and high resolution infrared spectra. Previously radiofrequency data [Chem. Phys. Lett. 214 (1993) 265–270] and millimeter data [J. Mol. Spectrosc. 131 (1988) 1–8] were combined with new millimeter and infrared measurements, and a set of 27 parameters has been derived. A multiple fit analysis was performed confirming the assumption that the ν6=1 excited state is not affected by intervibrational resonances.
