Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

• Autores: Henriette Wolpher, Magnus Borgström, Leif Hammarström, Jonas Bergquist, Villy Sundström, Stenbjörn Styring, Licheng Sun, Björn Åkermark
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 8, 2003, págs. 989-991
• Idioma: inglés
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• Resumen

  • A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown.