Franck-Condon factors and r-centroids were computed for the D^(2)Σ^(+) – A^(2)Π_(i) and D^(2)Σ^(+) – B^(2)Σ^(+) band systems of the aluminum oxide molecule for the v’ = 10; v” = 10 matrix using the method developed by Jarmain and McCallum. The latest Fourier-transform Spectrometer molecular constants of the ground and excited state are used. The intensities of these bands are discussed, and the Franck-Condon factors and r-centroids obey the established relationships.
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