Resumen de Fracture toughness of different monolithic zirconia upon post-sintering processes

Niwut Juntavee, Apa Juntavee, Thipradi Phattharasophachai

• Background: Surface treatments are expected to be a reason for alteration in fracture resistance of zirconia. This study evaluated the effect of post-sintering processes on the fracture toughness of different types of monolithic zirconia.

  Material and Methods: Classical- (Cz) and high-translucent (Hz) monolithic zirconia discs (1.2 mm thickness, 14 mm in Ø) were prepared, and randomly divided for surface treatments with 1) as-glazed (AG); 2) finished and polished (FP); 3) finished, polished, and overglazed (FPOG); and 4) finished, polished, and heat-treated (FPHT) technique (n=15/group). Fracture toughness (KIC) was determined with indentation fracture toughness method at load 1 kg for AG, FPOG and 10 kg for FP, FPHT with 15 sec dwelling time. Weibull analysis was applied for survival probability, Weibull modulus (m), and characteristic toughness (K0 ). Microstructures were examined with SEM and XRD. ANOVA and multiple comparisons were determined for significant differences (α=0.05).

  Results: The mean±sd value of KIC (MPa.m1/2), m, and K0 were 1.60±0.19, 7.27, 1.71 for CzAG; 9.57±0.89, 9.97, 10.96 for CzFP; 1.61±0.15, 10.56, 1.68 for CzFPOG; 6.45±0.31, 20.31, 6.60 for CzFPHT; 1.45±0.13, 10.91, 1.51 for HzAG; 6.58±0.24, 27.00, 6.70 for HzFP; 1.24±0.05, 23.90, 1.27 for HzFPOG; and 5.07±0.16, 30.51, 5.15 for HzFPHT. The KIC was significantly affected by the post-sintering process, type of zirconia (p<0.05). The Cz indicated a significantly higher KIC than Hz. The FP significantly enhanced KIC, while OG was unable to raise KIC. HT reduced KIC due to reverse phase transformation.

  Conclusions: Post-sintering processes caused alteration in fracture resistance of zirconia. Fracture toughness was enhanced with FP, but not with either OG or HT process for both Cz and Hz. Surface treatment of zirconia through a finished-polished process is recommended, while glazing and heat-treated are not suggested.