Na2CO3 Mediated Silver Mirror Reaction of General Aldehyde at Room Temperature
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Ronghui Que [1] ; Hongbo Wu [1] ; Yalan Zhao [1] ; Shasha Han [1] ; Min Han [1] ; Yan-Lin Xiong [1] ; Shanheng Ma [2] ; Houxiong Wang [2]
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[1] Anhui Normal University
Anhui Normal University
China
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[2] Central China Normal University
Central China Normal University
China
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- Localización: Journal of chemical education, ISSN 0021-9584, Vol. 100, Nº 2, 2023, págs. 880-884
- Idioma: inglés
- Texto completo no disponible (Saber más ...)
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Resumen
The classic silver mirror reaction at room temperature in textbooks usually used glucose to react with silver nitrate and ammonium nitrate with the presence of caustic alkalis. But the aldehydes such as acetaldehyde and propionaldehyde were difficult to react under the same condition. In this paper, Na2CO3 was used to mediate the reaction instead of caustic alkalis. In a newly formed ammoniacal-silver solution, a certain dose of Na2CO3 solution and aldehydes (formaldehyde, propionaldehyde, n-butyraldehyde and glucose) were added in, and then a silver mirror formed within 2 min at room temperature without stirring or continuous shaking. This result broadened the knowledge of silver mirror reactions with aldehydes and made the scheme simple and easy, enabling the teaching to be more interesting. A survey result showed that 68.4% of preservice teachers at Anhui Normal University are willing to teach the experiment using this improved method.
