Down conversion and efficient NIR to visible up-conversion emission analysis in Ho3+/Yb3+ co-doped tellurite glasses

• Autores: Sharafudeen Kaniyarakkal, Kesavulu Culala Rajasekharaudayar, Rajesh Dagupati, Yang Li, Zhi Chen, Vijayakumar Sadasivan Nair, Shiju Edappadikkunnummal
• Localización: Boletín de la Sociedad Española de Cerámica y Vidrio, ISSN 0366-3175, Vol. 62, Nº. 4, 2023, págs. 379-386
• Idioma: inglés
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• Resumen

  • A series of glasses with chemical composition (50−x−y) TeO2–30ZnO–10YF3–10NaF–xHo2O3–yYb2O3 (x=0.5 and y=0.5, 1.0, 3.0, 5.0mol%) were prepared by melt-quenching procedure. The absorption spectra, excitation, down conversion emission spectra, up-conversion (UC) emission spectra and decay time measurements were analyzed. In down conversion, the visible emission transition intensity associated with 5F4→5I8 (547nm), 5F5→5I8 (657nm), and 5F4→5I7 (755nm) of Ho3+ ions decreased with Yb3+ concentration due to the energy transfer (ET) process from Ho3+ to Yb3+ ions. In up-conversion, on exciting with 980nm diode laser beam, we observed a strong green (543nm) and red (657nm) UC emissions, that refers to the energy level transitions; 5F4 (5S2)→5I8 and 5F5→5I8 of Ho3+. The influence of excitation power on UC intensities studies revealed that the population at 5F4 (5S2) and 5F5 levels of Ho3+ ion occurs due to two-photon absorption process associated energy transfer from Yb3+ to Ho3+. The influence of Yb3+ doped concentration on UC was studied, and it is observed that both the green and red UC intensities improved significantly on increasing Yb3+ ions concentration.