Effect of preparation methods of ceo2-mnox mixed oxides on preferential oxidation of co in h2-rich gases over cuo-based catalysts

• LEI GONG ^[1] ; LAI-TAO LUO ^[1] ; RUI WANG ^[1] ; NING ZHANG ^[1]
  1. [1] Nanchang University

     Nanchang University

     China

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 57, Nº. 1, 2012, págs. 1048-1053
• Idioma: inglés
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• Resumen

  • The CeO2-MnOx mixed oxides were prepared by deposition-precipitation (DP) and surfactant-templated (CB) methods, and then used as the support of CuO/ CeO2-MnOx catalysts. The samples were characterized by means of XRD, BET, H2-TPR, CO-TPD and XPS. Results show that preparation methods of CeO2-MnOx support have a direct effect on the physicochemical properties and catalytic activities of CuO/CeO2-MnOx catalysts for the CO preferential oxidation in H2-rich gases(CO PROX). CuO/CeO2-MnOx (CB) catalyst exhibits higher CO conversion and stability in H2-rich gases than CuO/CeO2-MnOx (DP), with 100% conversion of CO at 140 °C after a temperature cycle, which indicates that CeO2-MnOx (CB) as support of CuO based catalyst is more useful for CO PROX reaction than CeO2-MnOx (DP). Compared with CuO/CeO2-MnOx (DP), there are richer oxygen vacancies and more Mn4+ species on the surface of CuO/CeO2-MnOx (CB), and stronger interaction between CeO2 and MnOx in it. More amounts of active copper species and complicated transfer of electrons density on CuO/CeO2-MnOx (CB) also favour the activity of the catalyst.