Study of ruggedness hs-spme procedure for organotin analysis by gc-pfpd

• MANUEL BRAVO ^[1] ; GÄETANE LESPES ^[2] ; WALDO QUIROZ ^[1] ; IDA DE GREGORI ^[1] ; HUGO PINOCHET ^[1] ; MARTINE POTIN- GAUTIER ^[2]
  1. [1] Pontificia Universidad Católica de Valparaíso

     Pontificia Universidad Católica de Valparaíso

     Valparaíso, Chile

     
  2. [2] Pontificia UnivUniversité de Pau et des Pays de L Adourersidad Católica de Valparaíso Laboratoire de Chimie Analytique, Bioinorganique et Environnement
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 54, Nº. 2, 2009, págs. 171-174
• Idioma: inglés
• Enlaces
  • Texto completo
• Resumen

  • In this work, the ruggedness of several variables suspected influents on extraction of ethylated organotins (butyl-and phenyltins) by Solid Phase Microextraction in headspace mode (HS-SPME) was realized by using Gas Chromatography-Pulsed Flame Photometric detection (GC-PFPD). The influence of eight factors on SPME procedure was analyzed using an 11-factor, 12-experiment Plackett-Burman design on the chromatographic area normalized to either Tripropyltin or Diheptyltin area. After the results, the extraction of OTC by HS-SPME could be considered as rather robust as the factor effects were generally not significant or small when both internal standards were used.