Synthesis and structure of dicarbonyldichloro{2-(diphenylphosphineoxide)pyridine}ruthenium(ii)

• OSCAR DÍAZ ^[1] ; SOLEDAD MEDINA ^[1] ; MAURICIO VALDERRAMA ^[1] ; FERNANDO J LAHOZ ^[2] ; M. LUISA MARTÍN ^[2]
  1. [1] Pontificia Universidad Católica de Chile

     Pontificia Universidad Católica de Chile

     Santiago, Chile

     
  2. [2] Universidad de Zaragoza-CSIC Instituto de Ciencia de Materiales de Aragón Departamento de Química Inorgánica
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 53, Nº. 2, 2008, págs. 1480-1482
• Idioma: inglés
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• Resumen

  • Reaction of the dinuclear complex [{Ru(CO)3Cl2}J with the Hgand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k²-PyPOPh2-N,0)(CO)2Cl2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structure was determined by single-crystal X-ray diffraction.