Lithium cobalt spinel oxide: A structural and electrochemical study

• ERIKA MEZA ^[1] ; DANIELA ALBURQUENQUE ^[1] ; JUAN ORTIZ ^[1] ; JUAN LUIS GAUTIER ^[1]
  1. [1] Universidad de Santiago de Chile

     Universidad de Santiago de Chile

     Santiago, Chile

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 53, Nº. 2, 2008, págs. 1494-1497
• Idioma: inglés
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• Resumen

  • Lithium cobaltite, LiCo(2)0(4), prepared by thermal decomposition of nitrates salts was synthesized at 400 °C. X-ray Rietveld refinement showed the presence of two phases: a cubic spinel (Co(3)0(4)) and other corresponding to spinel-like, which could not be classified as LiCo(2)0(4) or LiCo0(2) since both crystallized in Fd3m S.G. Electrochemical determinations (charge-discharge curves and impedance spectroscopy measurements) showed that Li+ ion is inserted into the spinel lattice, with D = 8 10-16 cm s-1 at 2.00-2.25 V potential range whereas lithium extraction occurred at 3.2-3.8 V potential range.