Thermal and x-ray crystallographic structural studies on (n,n-dibencyl)-4-nitrophenylsulfenamide

• Iván Brito ^[1] ; Ambrosio Restovic ^[1] ; Samuel Pedrero ^[1] ; Arlett Mancilla ^[1] ; Danitza Vargas ^[1] ; Yasna León ^[1] ; Eduardo Ramirez ^[1] ; Mauricio Arias ^[1] ; Kareen Brown ^[1] ; Aldo Alvarez ^[1] ; Alejandra Arancibia ^[1] ; Matías López-Rodriguez ^[2]
  1. [1] Universidad de Antofagasta

     Universidad de Antofagasta

     Antofagasta, Chile

     
  2. [2] Universidad de La Laguna

     Universidad de La Laguna

     San Cristóbal de La Laguna, España

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 48, Nº. 3, 2003, págs. 51-56
• Idioma: inglés
• Enlaces
  • Texto completo
• Resumen

  • Crystal and molecular structure and the thermal properties of (N,N-dibencyl)-4-nitrophenylsulfenamide, (C6H5CH2)2 NSC6H4-4-NO2, is herein presented. The structure is a divalent sulfur compound that crystallized in the monoclinic system, space group P2(1)/c with a=9.274(2), b=6.013(1), c=32.147(9) Å, b=95.55(2) and Dx=1.305 g cm-3 with Z=4. The plane C-S-N form a dihedral angle of 77.4(3) with the plane C19-N1-C20, and it represent a notable difference with other sulfenamides described in the literature. The thermogravimetric analysis reveal a decomposition of the product in two steps and another event, probably, associated to a endothermic phase transition