Resumen de Synthesis and Characterization of New Ruthenium Complexes With 11-carboxy-dipyrido (3,2-a: 2’,3’-c)phenazine as Ligand

Alejandra Arancibia, Ana Maria Leiva, Bárbara Loeb

• español

  En el presente trabajo se reporta un método general para la síntesis de complejos de Rutenio del tipo [(HOOC-dppz)2RuX2] y [(HOOC-dppz)RuL2](PF6)2 (X = Cl- ó SCN- , L = 2,2'-dipiridina ó 4,4'-dimetil-2,2'-dipiridina y HOOC-dppz = 11-carboxi-dipirido(3,2-a:2',3'-c)fenacina. Los complejos fueron caracterizados por métodos convencionales, como espectroscopías UV-Visible, IR y 1H-NMR y Voltametría Cíclica.

• English

  A general method for the synthesis of Ruthenium(II) complexes of the type [(HOOC-dppz)2RuX2] and [(HOOC-dppz)RuL2](PF6)2 (X = Cl- or SCN-, L = 2,2'-dipyridine or 4,4'-dimethyl-2,2'-dipyridine and HOOC-dppz = 11-carboxy-dipyrido(3,2-a:2',3'-c)phenazine), is reported. The complexes were characterized by conventional technics as UV-Visible, IR and 1H-NMR spectroscopies and cyclic voltammetry.